This is what IM Andrew Greet says about 5.exf5 in his fantastic book 'Play the Ruy Lopez':
"The immediate 5 exf5 (he recommends 5.0-0 instead) is also possible, and may end up transposing after one of black's likely replies of 5...Be7, 5...d6 or 5...Bc5. The move 5...Ne7!? is interesting though."
According to my database, after 5 exf5, 5...d6 is the most popular move, followed by 5...Bc5, then 5...Ne7.
Although I play the Ruy Lopez, I seldom see the Schliemann, and even if I did, I play 5.0-0, so I guess I don't have enough credibility to answer your question if 5...Ne7 or 5...d6 is better. However, if you want to give a few more moves after 5...Ne7 or 5...d6, I would be happy to check it through with database!
Hi, I have a question about an interesting position in the Ruy Lopez, Schliemann defense. What would be the best response for Black after White takes the f-pawn? Would 5...d6 be a good response or is 5...Ne7 even better? Thanks in advance for your help!