7.Bxc6 is not the strongest for a few reasons... after bxc6 Black has an excellent central pawn complex. Also it is unnecessary to capture the knight unprovoked - if black challenges the bishop with a6 perhaps you then decide to do it (although I might retreat the bishop instead), but other moves can be played eg. 0-0 or Bg5 to continue developing or even Nd5 if you want to get tricky. Anyway, the main issue is the Bb5 is slightly misplacing the bishop IMO. Qc7 is a standard square for the queen in many Sicilians but black would be less inclined to play it this early if Ndb5 was an option for white. Bb5 takes this option away. 6.Bg5 is normal I think, suggesting that you might damage blacks pawn structure with Bxf6.
13.Bxf6 is interesting... I'm not sure black can do too much with the g file, white can go Kh1 at some point, or g3 possibly. In any case, white now has a great knight on f5 which cannot be shifted by g6 from black. Plus the long term weakness of doubled pawns and the fact the Nf6 was influencing the d5 square. Black would love to play d5 safely and open things up (another common Sicilian theme, if black gets d5 safely he should be doing quite well). But it's not straightforward anyway, black has the bishop pair, semi open g file, but the longer term weakness of the doubled pawns and a slightly airy King over on the queenside.
There are two things here I am asking about. I am curious why Stockfish is saying to take or not take the knights on c6 and f6 and if the bishop pair is a factor with the first bishop.
I played 7. Bxc6. Why is this bad? Simply because of the bishop pair? Other reasons? Compare that with 13. Bxf6. Since one bishop is gone, does Stockfish not evaluate the second bishop as important on the board? In the game, I thought taking the N on f6 (the rook was already on g8 in the actual game) would line up an attack on my king even though pawns were doubled. So, why take the knight? Why not keep it and use it for a queenside attack while keeping the g file closed?