No, you can't block by countries. Those are self-reported anyway.
Block countries
Exactly. My bullet rating against Americans is over 150 points worse. I can't keep an eye on the time when playing 1 minute bullet. I always try to play at least as fast as my opponent. When I look at the clock in the middlegame against an American, I am already 20 seconds behind...

Hi,
Yes it's not possible as said above but as always worth suggesting to staff as if there is demand it could change.
https://support.chess.com/article/295-how-do-i-report-a-bug-or-make-a-suggestion
Thanks
Can I block certain countries? Lag is a huge issue in bullet games and some countries/regions seem to have an huge advantage in bullet games.