Perhaps the most obscure and least used moves in Chess is called En Passant. It can only occur when a player exercises his option to move his pawn two squares on its initial movement. When this happens, the opposing player has the option to take the moved pawn "en passant" as if it had only moved one square. This option, though, only stays open for one move.
http://www.conservativebookstore.com/chess/enpass.htm
The En passant capture must be done on the very next turn, or the right to do so is lost.
http://en.wikipedia.org/wiki/En_passant
Hope that helps!
can you only do the on passant right when the opposite player has just moved their pawn, or does the priveledge to do the on passant remain until one pawn or the other moves on?
thankyoyu